High-performance catalytic reduction of 4-nitrophenol to 4-aminophenol using M-BDC (M = Ag, Co, Cr, Mn, and Zr) metal-organic frameworks

Abstract

The catalytic activity of pure metal nanoparticles is always limited by aggregation during the reaction. Therefore, promising candidates such as metal-organic frameworks possess benefits due to their 3D porous structures, high stability, and high specific surface area. In this study, effective and reusable catalysts based on M-BDC metal-organic frameworks were synthesized utilizing five different coordinating metal ions (M = Ag, Co, Cr, Mn, and Zr) as metal nodes and 1-4-benzene dicarboxylic acid (BDC) as an organic linker and used in catalytic reduction of 4-Nitrophenol (4-NP) to 4-Aminophenol (4-AP) for the first time. The as-prepared catalysts were characterized using SEM, EDX, XRD, and FTIR techniques. Based on catalytic performance, Co-BDC showed the best catalytic efficiency compared to the other M-BDC MOF catalysts with a conversion yield of about 99.25 in 2 min. All of the catalysts could catalyze the complete reduction of 4-NP to 4-AP at different reaction times (2–10); however, Mn-BDC could not finish the catalytic reduction reaction even after 20 min. The two more efficient catalysts including Co-BDC and Cr-BDC demonstrated high stability and reusability (more than 85% catalytic efficiency) even after 5 cycles.