High-level waste activated sludge dewaterability using Fenton-like process based on pretreated zero valent scrap iron as an in-situ cycle iron donator

Abstract

A novel, recyclable, and rapid pre-ultrasound-thermal-acid-washed zero valent scrap iron/hydrogen peroxide (UTA-ZVSI/H2O2) method has been developed to effectively enhance waste activated sludge (WAS) dewaterability. The effects of UTA ultrasound densities, UTA temperature, newly generated iron solution, H2O2 concentrations, and WAS conditioning time on the WAS dewaterability were investigated using a bench-scale system. Results indicated that the UTA-ZVSI/H2O2 treatment significantly improved the WAS dewaterability. The water content of the dewatered cake decreased to 44.15 ± 0.98 wt% during optimal operational conditions, which was significantly lower than that achieved using Fenton-based processes. Based on this outcome, a three-step treatment mechanism involving UTA-ZVSI/H2O2 has been developed, including iron flocculation, hydroxyl radical oxidation, and skeleton building. The dewatering efficiencies of three types of representative WAS were consistently effective in the UTA-ZVSI/H2O2 reactor for up to 15 cycles. Efficiencies levels were significantly higher than those achieved with Fenton-based processes. Economic analysis illustrated that the developed UTA-ZVSI/H2O2 system was the most cost-effective among other WAS dewatering treatments. In addition, the treatment system significantly alleviated toxicity of heavy metals and phytotoxicity in the dewatered sludge. This supported subsequent agricultural use. In summary, this study provided a comprehensive and useful basis for improving WAS dewatering and subsequent disposal.