Abstract

Low hydrophilicity of membranes is probably the biggest concern in membrane filtration since it increases the costs for water treatment. Conversely, application of hydrophilic biopolymers (such as cellulose) is limited because of its complex and crystalline structure. Enabling the wide use of the most common biopolymer in nature is crucial to improve the performance of water treatment, especially in terms of membrane sustainability. Here, we study the effect of cellulose dissolution in the synthesis of homogeneous PVDF/cellulose membranes. Although only partial dissolution was achieved for studied samples, adding cellulose to the membranes greatly improved their water flux. Besides, the porous structure obtained after partial solvent removal indicates the water flux (and consequently the pore size) may be tailored according to the membrane production method. Therefore, the homogeneous cellulose microfiltration membranes studied here may have potential for water treatment considering their high-water flux and low complexity to produce.

Highlights

  • Water is considered a finite resource essential for life that is distributed around earth

  • The porous structure obtained after partial solvent removal indicates the Water flux (WF) may be tailored according to the membrane production method

  • The higher crystallinity index of Avicel cellulose nanocrystals (CNC) (~90%) compared to Bleached Eucalyptus Pulp (BEP) CNC (88%) is due to the higher purity of Avicel since it consists in pure cellulose rather than a mix of cellulose and hemicellulose in BEP (Malucelli et al 2018)

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Summary

Introduction

Water is considered a finite resource essential for life that is distributed around earth. New materials have been used to improve water treatment efficiency even further and to overcome the limitations of cellulose acetate membranes, especially the pH stability and rejection (Voicu et al 2015). One of these materials is polyvinylidene fluoride (PVDF), which is considered an ideal polymer in water treatment for its improved mechanical, chemical and thermal stability (Razzaghi et al 2014)

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