High-Entropy Layered Double Hydroxides with Highly Adjustable Components for Enhancing Electrocatalytic Oxygen Evolution.

Abstract

The main obstacle to the development of large-scale electrochemical hydrogen production based on water splitting is the slow four-electron kinetics of OER (oxygen evolution reaction). The most efficient method is to create sophisticated and effective OER catalysts. Here, we proposed the controlled synthesis of high-entropy layered double hydroxides (HELDH) for wide component regulation and the component design of high OER activity to make up for the restricted component regulation in conventional catalysts. Through the use of coprecipitation and hydrothermal synthesis, the representative sample (MgCoNi)3(FeAl)-LDH is created and systematically characterized. Significantly, this technique of preparation may generically synthesize a variety of HELDH with various component combinations, demonstrating the remarkable adaptability of the HELDH components. Subsequently, (FeCoNi)3(FeCr)-LDH with high OER activity is designed and synthesized. (FeCoNi)3(FeCr)-LDH shows excellent OER activity (overpotential is only 230 mV at 10 mA cm-2). A new platform for the creation of high-performance catalysts and high-entropy materials was established by the synthesis and design of HELDH.