Abstract
An innovative tactic to prepare porous organic polymer membranes was developed via interfacial azo-coupling polymerization. The membranes possess plentiful anchoring sites for loading Pd nanoparticles, and served as a membrane reactor, which exhibits high-performance catalytic reduction with a flux of 27.3 t m-2 day-1 and good long-term stability due to almost zero Pd leaching.
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