High-efficiency degradation of organic pollutants with Fe, N co-doped biochar catalysts via persulfate activation

Abstract

In this study, the Fe, N co-doped biochar (Fe-N-BC) was prepared by pyrolyzing wheat straw, urea and iron salts and used to activate persulfate (peroxydisulfate, PS) for organic contaminant degradation. Iron oxide doping not only introduced magnetism into the biochar for easy separation, but also influenced its catalytic ability for PS activation. In the Fe-N-BC/PS system, almost all acid orange (AO7) was removed within 90 min with an apparent rate constant (kobs) of 0.114 min−1, which was almost 37 times larger than that of pure N-BC (0.003 min−1). Factors influencing the removal of AO7 were investigated, including PS concentration, catalyst dosage, and initial pH. The Fe-N-BC/PS system had high removal efficiencies for various organic contaminants and showed high resistance to inorganic anions in aquatic environments. The radical quenching studies, electron paramagnetic resonance (EPR) measurements, and electrochemical analyses verified that the mechanism of AO7 degradation in the Fe-N-BC/PS system included both radical and non-radical pathways involving the generation of OH, SO4−, O2−, 1O2, and electron transfer. Additionally, persistent free radicals (PFRs) on the catalysts also related to their catalytic efficiencies. These results demonstrated that the Fe-N-BC/PS system had the potential for wastewater treatment applications.