Abstract

New host materials (BCz–DBT and BCz–DBF) are synthesized by regrouped 3,3-bicarbazole (BCz) and dibenzothiophene (DBT)/dibenzofuran (DBF). Their thermal, electrochemical, electronic absorption and photoluminescent properties are also carefully investigated. The materials exhibit high glass transition temperatures (Tg) of 134°C and 139°C, respectively. This kind of molecular design can effectively achieve high triplet energies and suitable highest occupied molecular orbital and lowest unoccupied molecular orbital (HOMO/LUMO) energy levels. High external quantum efficiencies (EQE) of sky blue (EQE=25%) and three-color white (EQE=21.4%) phosphorescent OLEDs have been achieved by using BCz–DBF as the host material.

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