High efficiency adsorption of uranium by magnesia-silica-fluoride co-doped hydroxyapatite

Abstract

Hydroxyapatite has a high affinity to uranium, and element doping can effectively improve its adsorption performance. In this study, magnesia-silica-fluoride co-doped hydroxyapatite composite was prepared by hydrothermal method, and the effect of single-phase and multiphase doping on the structure and properties of the composites was investigated. The results showed that the specific surface area of Mg–Si–F-nHA composites increased by 63.01% after doping. Comparing with nHA, U(VI) adsorption capacity of Si-nHA, Mg–Si-nHA and Mg–Si–F-nHA composites increased by 13.01%, 17.39% and 22.03%, respectively. The adsorption capacity of Mg–Si–F-nHA composite reached 1286.76 mg/g. Adsorbent dosage and pH obviously affected U(VI) adsorption, and the experimental data can be fitted well by PSO and Sips models. The physicochemical characterization before and after adsorption suggested that complexation, ion exchange and precipitation participated in uranium adsorption. In conclusion, different elements doping can effectively improve the uranium adsorption properties of hydroxyapatite composites.