Abstract
In this work we studied the AgI–AgPO3 and AgPO3 glasses obtained in high and low temperature syntheses. The mechanosynthesis and melt-quenching methods were employed to prepare the amorphous materials. Samples were investigated by means of X-ray diffraction, modulated differential scanning calorimetry and Raman spectroscopy. Despite the identical overall chemical composition of the glasses, we noticed different values of glass transition, non-reversing enthalpy and unequal phase composition in elevated temperatures. The work discusses differences in the glass network and distribution of its components induced by different energy transfer mechanisms of each synthesis method.
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