Hierarchically Plasmonic Z-Scheme Photocatalyst of Ag/AgCl Nanocrystals Decorated Mesoporous Single-Crystalline Metastable Bi20TiO32 Nanosheets

Abstract

The hierarchical photocatalysts of Ag–AgCl@Bi20TiO32 composites have been successfully synthesized by anchoring Ag–AgCl nanocrystals on the surfaces of mesoporous single-crystalline metastable Bi20TiO32 nanosheets via a two-stage strategy for excellent visible-light-driven photocatalytic activities in the Z-scheme system. First, the single-crystalline metastable Bi20TiO32 nanosheets with tetragonal structures were prepared via a facile hydrothermal process in assistance with the post-heat-treatment route using benzyl alcohol. Especially, the mesoporous Bi20TiO32 nanosheets showed high photocatalytic activity for the degradation of rhodamine B dye under visible-light irradiation. Then, the as-prepared mesoporous Bi20TiO32 nanosheets were used as a support for loading Ag–AgCl nanocrystals using the deposition–precipitation method and irradiation–reduction process to fabricate the Ag–AgCl@Bi20TiO32 composites. Inspiringly, the hierarchical Ag–AgCl@Bi20TiO32 photocatalyst has the higher photocatalytic perform...