Hierarchical porous structured polysulfide supported nZVI/biochar and efficient immobilization of selenium in the soil

Abstract

Soil pollution with selenium is a significant environmental problem in several areas of the world, which extremely affects the growth of plants and human health. Thus, it is necessary to find an effective method to immobilize selenium in the soil to make it less bioavailable and less accessible. In this study, the low-cost biochar-supported nanoscale zero-valent iron and polysulfide (PS-nZVI@BC) are produced and used for the immobilization of selenium (Se) in soil. The FTIR, UV–Vis, XRD, VSM, SEM and XPS techniques validate surface properties and morphology of PS-nZVI@BC. Introduction of S2− led to the in-situ formation of FeS on the surface of the biochar supported zero valent iron. Two intense Bragg peaks (2θ) of 40.5°, 44.5° were corresponded to Fe0 basal plane, indicating the presence of nZVI in nZVI@BC and PS-nZVI@BC. The modified biochar presents a magnetic saturation value of 0.008 emu/mg, reasonably less than the reported values of bare nZVI. The soil immobilization showed that the PS-nZVI@BC is more effective for the control of selenium than the biochar and nZVI@BC. The available selenium content decreased by 77.29% in PS-nZVI@BC amended soil after 30 days. From sequential extraction procedure (SEP) results, it was observed that PS-nZVI@BC promoted the conversion of more accessible Se (water-soluble and exchangeable fractions) into the less accessible forms (acid-soluble, organic, and residual fractions) to reduce the toxicity of Se. Surface sorption, reduction and complexation were dominant mechanisms for Se immobilization. Hence, PS-nZVI@BC is promising and effective for immobilizing Se in contaminated soils and improving the soil properties.