Hierarchical NiZn Solid Solution as a Highly Efficient Palladium Free Heterogeneous Catalyst for Suzuki-Miyaura Cross-Coupling Reaction.

Abstract

In this report, surfactant free solid solution of NiZn with a hierarchical architecture was synthesized via a one-pot colloidal approach. Evidence supporting hierarchical crystal growth and alloying of metals at the atomic level was obtained from field emission scanning electron microscopy and transmission electron microscopy-energy-dispersive X-ray data. Lattice sites of face-centered metallic Ni were found to be occupied by Zn as evident from powder X-ray diffraction where a gradual shift in the peak position and increase in the average lattice parameter upon reduction of the Ni content in the alloy samples can be observed. This well-alloyed, magnetically separable, non-noble metal-based solid solution has the potential to replace the palladium-based catalyst in the Suzuki-Miyaura cross-coupling of aryl halides (-Cl/-Br) and phenylboronic acid. The nanostructured catalyst was formed through the assembly of a triangular spiked and sheet-like structure and is magnetically well separable that is stable enough under the catalytic reaction condition. The developed heterogeneous catalyst and the designed economical catalytic model are the first ever reported work. The catalytic results outperformed most of the reported state-of-the-art works involving the transition metal-based catalyst.