Hierarchical MoS2-Based Onion-Flower-like Nanostructures with and without Seedpods via Hydrothermal Route Exhibiting Low Turn-on Field Emission

Abstract

Herein, we report facile hydrothermal synthesis of hierarchical MoS2 -based nanomorphs (displaying onion-flower-like features) with the primary focus on field-emitter applications. The synthesized nanostructures were characterized physicochemically to understand their basic structural and morphological features. Interesting nanoscale morphological evolution of onion-flower-like MoS2—from plain nanoflowers to those containing seedpods—is observed with the change in hydrothermal reaction time from 9 h to 21 h. Peculiarly, MoS2 nanomorphs with only onion-flower-like morphology displayed lower turn-on field value of 3.7 V/μm as compared to 4.2 V/μm for the nanoflowers containing seedpod-like particles. This might be attributed to the possibility of an easy electron conduction path available for the petals in plain nanoflowers, which may be impeded by the seedpod-like particles in the latter case.