Abstract
Reaction of HgBr2 with sodium cyclohexanethiolate in methanol, followed by recrystallisation from pyridine, gives the discrete molecular complex [Hg7(SC6H11)12Br2], in which six Hg atoms form a distroted octahedron around a central Br, thiolate ligands are bridging or terminal, and a HgBr unit with terminal Br caps three thiolates on one side of the molecule.
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