Abstract

Some literature reports have shown the existence of short Hg(II)⋅⋅⋅d8 [M] (M=Pd, Pt) contacts between linear Hg(II) and square planar d8 [M] complexes that have been defined as heterometallophilic interactions. Linear L-Hg(II)-L complexes exhibit a π-hole or positive belt of electrostatic potential at the Hg atom, whereas late transition metals can serve as effective electron donors through their filled dz 2 orbitals. This study provides compelling evidence that Hg(II)⋅⋅⋅d8 [M] interactions should be more appropriately termed spodium bonds.

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.