Abstract
In the crystal structure of the title complex, [Co(H2O)6](L)2 (L = isonicotinate N-oxide, C6H4NO3), the CoII center, on a special position with site symmetry 2/m, is in an elongated octahedral environment composed of six coordinated water molecules. Each water ligand forms two strong O—H⋯O hydrogen bonds with the adjacent isonicotinate N-oxide counter-ions, which lie on mirror planes, forming a three-dimensional hydrogen-bonding supramolecular architecture.
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