Abstract
The first Fe-implanted polyoxotantalate (POTa), K12Na14H7.4[Fe10.7Ta1.3O8(OH)8(H2O)2(Ta6O19)6]·114.5H2O (1), has been obtained by self-assembly in alkaline solution. The polyanion consists of six Lindqvist-type {Ta6} units linked together by {Fe10.7Ta1.3}. The compound not only possesses the highest nuclearity transition metal-oxygen cluster, but also has the highest degree of polymerization in the POTa field to date. And 1 possesses remarkable proton conduction.
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