Abstract

Hexadiene formation from 2-propanol was investigated in view of acid-base properties of Ca−P−O catalysts with the Ca/P atomic ratio varying from 1.5 to 5.0. The catalytic activity in hexadiene formation increased up to a maximum at Ca/P=2.0, having almost the same amount of weak acidic sites as weak basic sites, and decreased with futher increase in Ca/P ratio.

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