Abstract
The concentrations, spatial distribution, diastereoisomer-specific profiles of hexabromocyclododecanes (HBCDs) in surface sediments from three major rivers in Shanghai as well as the seasonal variation of HBCDs were investigated. The concentrations of total HBCD diastereoisomers ranged from 0.05 to 6.87ngg−1dw. Significant spatial distribution of total HBCDs concentrations were observed. The mean concentration of total HBCDs followed the order of Suzhou Creek (2.00ngg−1)>Huangpu River (1.59ngg−1)>Yunzao Creek (0.77ngg−1). The concentration was a relatively low HBCDs level compared to levels measured in domestic and other parts of the world. The proportions of α-HBCD in sediment samples were generally higher than that of commercial formulations. This might be due to thermal isomerization from γ-HBCD to α-HBCD and slower degradation rate of α-HBCD compared to γ-HBCD in anaerobic conditions. The concentrations of ΣHBCD in the summer were significantly higher than those in the winter (paired t test, p<0.01). This seasonal variation could probably be attributed to a combined effect of temperature and wet deposition. Moreover, a poor and no significant correlation between ΣHBCD levels and TOC content in sediments was observed, suggesting that the spatial distributions of HBCDs were not constrained by the TOC in sediments of Shanghai.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
