Abstract
The title compound, [Zn(H2O)6]Cl2·2C6H12N4·4H2O, has been prepared under mild hydrothermal conditions. The ZnII atom, located on a centre of symmetry, is coordinated by six water molecules in a distorted octahedral coordination geometry. The hexamethylenetetramine molecule is not coordinated to ZnII but links the Zn complexes via three O—H⋯N hydrogen bonds. The remaining N atom of the hexamethylenetetramine molecule is hydrogen-bonded to a solvent water molecule. In the crystal structure, intermolecular O—H⋯O, O—H⋯N and O—H⋯Cl hydrogen bonds link the components into a three-dimensional network.
Highlights
The title compound, [Zn(H2O)6]Cl22C6H12N44H2O, has been prepared under mild hydrothermal conditions
The remaining N atom of the hexamethylenetetramine molecule is hydrogen-bonded to a solvent water molecule
Symmetry codes: (ii) x, y, z−1; (iii) −x+1, −y+1, −z+1; (iv) x, y−1, z; (v) −x, −y+1, −z+1; (vi) −x, −y, −z+1
Summary
R factor = 0.038; wR factor = 0.113; data-to-parameter ratio = 17.1. The title compound, [Zn(H2O)6]Cl22C6H12N44H2O, has been prepared under mild hydrothermal conditions. The ZnII atom, located on a centre of symmetry, is coordinated by six water molecules in a distorted octahedral coordination geometry
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