Abstract
The title compound, [Zn(H2O)6][H3NC10H5(SO3)2]2·4H2O (Zn site symmetry \overline{1}), is isostructural with its nickel(II) and cobalt(II) analogues. An extensive network of N—H⋯O and O—H⋯O hydrogen bonds involving the ammonio group, water molecules, and sulfonate O atoms helps to establish the packing. One of the uncoordinated water molecules is disordered over at least two sites (modelled over two positions with site occupancy ratio ca 2:1).
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