Heterostructured Ag@MOF-801/MIL-88A(Fe) Nanocomposite as a Biocompatible Photocatalyst for Degradation of Reactive Black 5 under Visible Light.

Abstract

Heterostructured Ag@MOF-801/MIL-88A(Fe) nanocomposite was synthesized through template effects in metal-organic frameworks (MOFs). MIL-88A(Fe) was fabricated on a MOF-801 template using the internal extended growth method (IEGM) via polyvinylpyrrolidone (PVP) as the structure-director agent to create the MIL-88A(Fe)-on-MOF-801 heterostructure. The MOF-801/MIL-88A(Fe) heterostructure was used as a template for the formation of Ag nanoparticles (NPs) inside it via a double solvents method (DSM) combined with a photoreduction route (PR). To characterize synthesized samples to a high level of detail, PXRD, FT-IR, EDX, N2 adsorption-desorption isotherms, TEM, DRS, PL, EIS, and Mott-Sckottky measurements were used. The resulting Ag@MOF-801/MIL-88A(Fe) nanocomposite demonstrated the highest photocatalytic activity of 91.72% for the degradation of Reactive Black 5, after 30 min under visible light irradiation.