Heterosilicates with Tetrahedral-Octahedral Frameworks: Mineralogical and Crystal-Chemical Aspects

Abstract

Research Article| January 01, 2005 Heterosilicates with Tetrahedral-Octahedral Frameworks: Mineralogical and Crystal-Chemical Aspects Nikita V. Chukanov; Nikita V. Chukanov 1Institute of Problems of Chemical Physics, 142432 Chernogolovka, Moscow Region, Russia, chukanov@icp.ac.ru Search for other works by this author on: GSW Google Scholar Igor V. Pekov Igor V. Pekov 2Faculty of Geology, Moscow State University 119899 Moscow, Russia Search for other works by this author on: GSW Google Scholar Author and Article Information Nikita V. Chukanov 1Institute of Problems of Chemical Physics, 142432 Chernogolovka, Moscow Region, Russia, chukanov@icp.ac.ru Igor V. Pekov 2Faculty of Geology, Moscow State University 119899 Moscow, Russia Publisher: Mineralogical Society of America First Online: 03 Mar 2017 © The Mineralogical Society Of America Reviews in Mineralogy and Geochemistry (2005) 57 (1): 105–143. https://doi.org/10.2138/rmg.2005.57.4 Article history First Online: 03 Mar 2017 Cite View This Citation Add to Citation Manager Share Icon Share Facebook Twitter LinkedIn MailTo Tools Icon Tools Get Permissions Search Site Citation Nikita V. Chukanov, Igor V. Pekov; Heterosilicates with Tetrahedral-Octahedral Frameworks: Mineralogical and Crystal-Chemical Aspects. Reviews in Mineralogy and Geochemistry 2005;; 57 (1): 105–143. doi: https://doi.org/10.2138/rmg.2005.57.4 Download citation file: Ris (Zotero) Refmanager EasyBib Bookends Mendeley Papers EndNote RefWorks BibTex toolbar search Search Dropdown Menu toolbar search search input Search input auto suggest filter your search All ContentBy SocietyReviews in Mineralogy and Geochemistry Search Advanced Search Steady progress in methods of synthesis and investigation of physical properties and crystal-chemical features of silicate microporous materials with transition elements (so-called zeolite-like amphoterosilicates) took place during the last decade. Materials of this type are promising ion exchangers, sorbents, catalysts or catalyst carriers and, accordingly, can be used in chromatography, catalysis, water purification, etc. Unlike common zeolites being aluminosilicates, frameworks of amphoterosilicates with transition metals are built of both tetrahedral fragments and “strong” cations (Ti, Nb, Zr, Ta, Sn, W, Fe, Mn, Zn, etc., see Chukanov et al. 2004) with coordination numbers 6 or 5. Structural and chemical diversity... You do not have access to this content, please speak to your institutional administrator if you feel you should have access.