Abstract
Molecular nanomagnets containing heterometallic 3d-4f complexes have been investigated extensively for the past few years realizing the role of exchange interaction to minimize the QTM effect. In this context, heterometallic complexes particularly containing CuII-LnIII have encompassed a pivotal role due to the ferromagnetic exchange interaction. Herein we review the Cu/Ln complexes that exhibit single molecule magnet (SMM)/magnetocaloric effect (MCE) in a comprehensive way.
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