Abstract
Cooperation of soft and hard bridging ligands (μ-S and μ-O, respectively) is crucial to the mechanism of heterolytic dihydrogen activation by germanium–ruthenium complex 1 to give syn and anti isomers of the corresponding hydroxogermanium–hydridoruthenium complex 2 (see scheme; dep=2,6-diethylphenyl). Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2008/z704899_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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