Abstract
The synthesis and reactivity of [Formula: see text]-bridged diiron macrocyclic complexes have been a topic of increasing interest in recent years since the observation of particular catalytic properties of these complexes. Herein, we report a preparation of a novel heteroleptic μ-nitrido diiron complex with unsubstituted phthalocyanine and octapropylporphyrazine macrocycles. This complex reacts with [Formula: see text]-chloroperbenzoic acid to form high-valent diiron oxo species showing strong oxidizing properties. The formation and structure of the transient oxo species was investigated by cryospray collision induced dissociation MS/MS technique. Analysis of fragmentation pattern showed that the attachment of oxo moiety occurred at either iron phthalocyanine or at iron porphyrazine site with slight preference for the phthalocyanine iron site. The catalytic properties of the heteroleptic μ-nitrido diiron complex were evaluated in the oxidative transformation of hexafluorobenzene and perfluoro(allylbenzene).
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
