Abstract
AbstractThe first heterogeneously catalyzed oxidative dehydrogenative cross‐coupling of aryl amines is reported herein. 2‐Naphthylamine analogues were reacted with various electron‐rich arenes using a heterogeneous Rh/C catalyst under mild aerobic conditions, thus affording nonsymmetrical biaryl amines in excellent yields with high selectivities. This reaction provides a mild, operationally simple, and efficient approach for the synthesis of biaryls which are important to pharmaceutical and materials chemistry.
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