Abstract

A novel ceramic electrode for redox catalysis was prepared from etched titanium sheet which was covered with a solution of titanium acetylacetonate in HNO3 and heated at 450°C. Noteworthy are the current densities recorded (for example 5 A/dm2) on such an activated electrode. This electrode has been used for the reduction of nitrobenzene. It proceeds as follows with reformation of Ti(OH)4:

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