Heterogeneous poly(ionic liquids) catalyst on nanofiber-like palygorskite supports for biodiesel production

Abstract

New heterogeneous poly(ionic liquids) catalysts (PAL-PILs) were successfully prepared by grafting polymerization of acid ionic liquids (ILs) (1-butysulfonate-3-vinylimidazole hydrogen sulfate) onto nanofiber-like palygorskite (PAL) supports that had been, in advance, covalently modified by γ-methacryloxypropyl trimethoxy silane (OPAL). Using the ester yields and PILs grafting degrees as main indexes, the optimized immobilization conditions were that the mass ratio of OPAL to ILs monomer was 1:2, the immobilization temperature and time were 60°C and 30h, the initiator (2,2′-Azobis(2-methylpropionitrile) dosage was about 5wt%, respectively. Then, the esterification between methanol and oleic acid was carried out to investigate the catalytic properties of PAL-PILs. For the homogeneous ILs catalyst, the yield of methyl oleate was about 85%. For the PAL-PILs, on which only about 41% of ILs used in homogeneous catalysis was immobilized, the yield could reach over 69% after reacting only 5h at 75°C at atmospheric pressure, when the molar ratio of methanol to oleic acid is adjusted to 12:1. More importantly, the yield of methyl oleate still maintained at about 22% after 6 recycling experiments. Moreover, the PAL-PILs catalysts exhibited efficient catalytic properties and could be recycled easily. These results offer great potential for the PAL-PILs in the biodiesel production for further research.