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Abstract
Solutions of uranoborates MII(BUO5)2·nH2O (MII=Mn, Co, Ni, Zn) in aqueous mineral acids at 25°C are studied. Based on experimental data on the solubility of uranoborates in hydrochloric acid, a quantitative model of the system crystalline uranoborate-aqueous solution is suggested. The model is used to predict the state of the investigated heterogeneous systems under various conditions, and also to estimate the standard thermodynamic functions of the indicated series of uranoborates.
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