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Abstract
Studies have been made in heterogeneous hydrogenations on the possible enantioselective effects of precursors of binol-phospates, which proved to be active and effective chiral ligands in homogeneous catalysis. It was to find out, whether a modifier with axial chirality could be used in heterogeneous hydrogenations if it meets certain structural requirements. Our results show that while the conversions reach 100%, the enantiodifferentiation was negligible.
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