Abstract

Heterogeneity in the formation of multihollow structure among styrene-methacrylic acid copolymer particles, which were produced by emulsion copolymerization, by the alkali/cooling method under partial neutralization conditions with potassium hydroxide was investigated. There was a threshold acid content to form the multihollow structure. The heterogeneity among the multihollow particles was based on the heterogeneity of acid contents among the original particles.

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