Abstract
Heteroepitaxy of complex oxide thin films is a significant challenge when a large mismatch in the lattice parameters (>8%) and difference in the crystallographic symmetry coexist between the film and substrate. Herein, the heteroepitaxial growth of a hexagonal delafossite CuFeO2 thin film with (00.1) orientation on a cubic perovskite (001) SrTiO3 substrate through translational and rotational domain matching epitaxy is reported. The rotational in‐plane domain orientation relationships are CuFeO2 [11.0]//SrTiO3 [110] and CuFeO2 [2.0]//SrTiO3 [110] with about 10% in‐plane lattice mismatch. The 14.8 nm‐thick (00.1) CuFeO2 thin film shows high‐crystalline quality with a full width at half maximum of rocking curve of about 0.24° and exhibits a possible indirect optical bandgap of 1.43 eV or direct optical bandgap of 1.94 eV. Herein, not only a model system demonstrating translational and rotational domain matching heteroepitaxy of complex oxides is reported, but also a way to thin‐film heterostructures integrating hexagonal delafossite with cubic perovskite materials for functional oxide devices is opened.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: physica status solidi (RRL) – Rapid Research Letters
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
