Heteroditopic Ru(II)– and Ir(III)–NHC Complexes with Pendant 1,2,3-Triazole/Triazolylidene Groups: Stereoelectronic Impact on Transfer Hydrogenation of Unsaturated Compounds

Praseetha Mathoor Illam,Arnab Rit,S N R Donthireddy,Sayantan Chakrabartty

doi:10.1021/acs.organomet.9b00156

Heteroditopic Ru(II)– and Ir(III)–NHC Complexes with Pendant 1,2,3-Triazole/Triazolylidene Groups: Stereoelectronic Impact on Transfer Hydrogenation of Unsaturated Compounds

Praseetha Mathoor Illam, Arnab Rit + Show 2 more

https://doi.org/10.1021/acs.organomet.9b00156

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Journal: Organometallics	Publication Date: Jun 26, 2019
Citations: 34

Affiliation: Indian Institute of Technology Madras

#Ligands In Homogeneous Catalysis #II)/Ir + Show 4 more

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Abstract

Imidazol-2-ylidene (ImNHC) and 1,2,3-traizol-5-ylidene (tzNHC) have been established as important classes of carbene ligands in homogeneous catalysis. To develop Ru(II)/Ir(III) complexes based on t...

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