Heterobinuclear Vinyl, Allyl, and Related Complexes of Rhodium/Osmium from Terminal Alkynes and Allenes, Vinyl to Carbene Transformations, and the Structures of [RhOs(C(CH3)CH2)(CO)3(Ph2PCH2PPh2)2] and [RhOs(C(CH3)C(CH3)2)(CH3)(CO)3(Ph2PCH2PPh2)2][CF3SO3

Abstract

This paper reports the synthesis and characterization of a series of vinyl, vinyl−hydride, vinyl−alkyl, and related heterobimetallic complexes of Rh and Os. Reductive elimination reactions of the v...