Abstract

A convenient new synthesis of trans-Ru(CO)3(μ-L)2 [L=2-(diphenylphosphino)pyridine, N-(diphenylphosphinomethyl)morpholine)] was developed. The reactions of these two tridentate organometallic ligands with selected group 11 and 12 metal salts resulted in the formation of hetero-binuclear Ru0→Mn+ [M=Ag(I), n=1; Hg(II), Cd(II), n=2] complexes with Ru–Ag=2.7132(7) A, Ru–Hg=2.7075(4) A and Ru–Cd=2.7750(9) A, as determined by X-ray crystallography.

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