Abstract

A little attempt has been made to get in touch with the green chemistry studying the successful occurrence of oxidation of 4-chlorobenzyl alcohol to 4-chlorobenzaldehyde in micellar media by Cr(VI), and its kinetics has been recorded spectrophotometrically following pseudo-first-order reaction conditions at λmax = 440 nm. In this purpose, some common hetero-aromatic bases like 2-picolinic acid, 1,10-phenanthroline and 2,2′-bipyridine have been utilized successfully for many fold rate enhancement of the reaction. Necessary spectroscopic evidences have been produced in support of the product formation.

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