Hemp Seed Oil and Oilseed Radish Oil as New Sources of Raw Materials for the Synthesis of Bio-Polyols for Open-Cell Polyurethane Foams.

Abstract

We report on the development of open-cell polyurethane foams based on bio-polyols from vegetable oils: hemp seed oil, oilseed radish oil, rapeseed oil and used rapeseed cooking oil. The crude oils were pressed from seeds and subjected to an optimal solvent-free epoxidation process. Bio-polyols were obtained by a ring-opening reaction using diethylene glycol and tetrafluoroboric acid as catalysts. The resultant foams were analysed in terms of their apparent density, thermal conductivity coefficient, mechanical strength, closed cell content, short-term water absorption and water vapour permeability, while their morphology was examined using scanning electron microscopy. It was found that regardless of the properties of the oils, especially the content of unsaturated bonds, it was possible to obtain bio-polyols with very similar properties. The foams were characterized by apparent densities ranging from 11.2 to 12.1 kg/m3, thermal conductivity of <39 mW/m∙K, open cell contents of >97% and high water vapour permeability.