Hematite-facilitated pyrolysis: An innovative method for remediating soils contaminated with heavy hydrocarbons

Abstract

As a recalcitrant fraction of petroleum, heavy hydrocarbons (including aromatics, resins, and asphaltenes) can remain in contaminated soils even after decades of weathering, thereby causing serious harm to the soil ecosystem and human health. Pyrolysis is a promising technique for remediating petroleum-contaminated soil. However, this technique still presents some drawbacks, such as high energy consumption and damage to soil properties. Therefore, an innovative method using hematite (Fe2O3) for the catalytic pyrolysis of weathered petroleum-contaminated soil was developed in this study. Compared with soil pyrolyzed without Fe2O3 at 400 °C for 30 min, the residual concentrations of aromatics, resins, and asphaltenes in soil pyrolyzed with 5.0% Fe2O3 were reduced by 67.8%, 52.3%, and 67.9%, respectively. After pyrolysis with 5.0% Fe2O3, the water-holding capacity of soil was considerably increased and the soil became darker and rougher. Scanning electron microscopy analysis showed that many small holes occurred on the surface of the pyrolytic soil. X-ray photoelectron spectrometer analysis showed that a thin layer of graphitic C was formed and deposited on the surface of the pyrolytic soil. We also observed that the wheat germination percentage and biomass yield in the soil pyrolyzed with 5.0% Fe2O3 were even higher than those in clean soil.