Helium enrichment mechanism of helium-rich gas reservoirs in central and western China: Degassing and accumulation from ancient groundwater

Abstract

Helium, a coordinated resource in natural gas, is an essential and strategic resource, but research on its enrichment mechanism is relatively weak. This study investigated helium enrichment in major reservoirs in China using geochemical methods to address the challenging topic of how helium accumulates in helium-rich gas reservoirs. It concludes that helium is enriched in a few reservoirs which capture additional helium exsolution from ancient groundwater. Released dissolved helium from ancient groundwater into the reservoir is the main mechanism of helium accumulation in helium-rich gas reservoirs. This was the first time that the concept of “multiple sources of helium supply and primary sources of helium enrichment” was applied to guide the formation of helium-rich gas reservoirs. Moreover, the main sources of helium comes from the radioactive decay of uranium (U) and thorium (Th) in hydrocarbon rocks, reservoirs, and the decay of U and Th dissolved in groundwater from other rocks. When dissolved helium in ancient groundwater crosses free gas or gas reservoirs, the partial pressure of helium in the water is significantly higher than the partial pressure of helium in the free gas or gas reservoirs, proving Henry's Law which states that the helium in the water is almost completely exsolution into the gas reservoir, forming a helium-rich gas reservoir.