Helical metal cage of silver(I) and mercury(II)-N-heterocyclic carbene complexes of 1,4-phenylene-bis{imidazo[1,5-a]pyridine-4-iumhexaflurophosphate}

Abstract

Novel N-heterocyclic carbene (NHC) architecture of 1,4-phenylene-bis{imidazo[1,5-a]pyridine-4 iumhexaflurophosphate}, [1(HPF6)2] has been synthesized in two steps from commercially available starting materials. The p-phylene bridged free annulated imidazolium salt has been synthesized and characterized both in solution and solid-state and has been used to synthesize silver(I) and mercury(II)-NHC complexes using the basic metal precursors. The [Ag2(1)2][PF6]2 (2) was synthesized using [1(HPF6)2] by Ag2O method in acceptable yield. The dinuclear Hg(II) complex [Hg2(1)2][PF6]4 (3) consisting of two biscarbene ligand has been synthesized from Hg(OAc)2 and [1(HPF6)2]. The helical nature of Hg(II)-NHC (3) has been established from solid state X-ray structure.