Abstract
The templated dimine-containing complexes, [M(SpyNpy 2)](ClO 4) 2·0.5H 2O {where M = Zn II, Cd II or Hg II}, exhibit chirality in solution (NMR) which is consistent with, and may be diagnostic of, a helical coordination array in these complexes as verified by the X-ray crystal structure of an enantiomer of the zinc(II) derivative.
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