Abstract
AbstractHelferich glycosylation reaction has been used to synthesizeO‐glycosides from protected glycosyl bromide and alcohol (or another carbohydrate) in the presence of mercuric cyanide. It is also referred to as the Helferich condition. This reaction involves the SN2 substitution mechanism leads the formation of β‐glycoside and release of HgCNBr. This reaction has been used in the preparation of glycosides.
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