Abstract
cis, cis, cis-1,2,3,4-Tetrakis(diphenylphosphinomethyl)cyclopentane/ 1 2 [PdCl(C3H5)]2 system catalyses efficiently the Heck reaction of heteroaryl halides with n-butyl acrylate, styrene, vinylpyridine and vinyl ether derivatives. High turnover numbers can be obtained for the reactions with halo pyridines, quinolines, furans or thiophenes.
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