Heavy-Crude-Oil Upgrading With Transition Metals

Abstract

Abstract In this paper are discussed the effects of some metallic oxides used to upgrade the heavy crude oil properties. The underlying objective is to increase the mobility of the oil in the reservoir by reducing viscosity and improving the oil quality using alumina supported transition metals and liquid phase transition metals catalysts (derived from either acetylacetonate or alkylhexanoate compounds), both homogeneously mixed with heavy crude oil. This heavy crude oil upgrading is based on the decrement of the asphaltenes, resins, and sulfur contents, and the increment of its API gravity, and strong reduction of viscosity. In the present work the heavy crude oil from the Golf of Mexico was studied. The API gravity was increased from 12.5 to 21-26, the kinematics viscosity was decreased from 18,130 to 100-8 cSt (at 298 K), the asphaltene content was reduced from 26 to 7 wt%, the sulfur was removed in the range of 30 to 60 wt%, and the distillable fraction was increased between 20 to 30 wt%, and determinated by Simulated Distillation and True Boiling Point (TBP).