Heavy oil atmospheric residue: HDS performance and life test using ARDS catalysts system

Abstract

The objective of this study is to evaluate the catalyst by introducing atmospheric residue of heavy crude (H-AR) that secures full comprehensive characteristics and converts into a petroleum product, namely low sulfur fuel oil (LSFO). Furthermore, to estimate the catalyst’s lifespan under hydroprocessing conditions by monitoring its deactivation rate and maintaining consistent sulfur in LSFO products through gradual increases in reaction temperature. Prior to the hydrotreating test, the heavy crude oil underwent desalting, dewatering, and atmospheric distillation to obtained atmospheric residue (H-AR, i.e., 350°C+) for use as feedstock. The pilot plant employed a catalyst system comprising both hydrodemetallization (HDM) and hydrodesulfurization (HDS) catalysts, distributed across two fixed-bed reactors. The results showed the lifespan approximately 3.0 months as a function of time-on-stream (TOS). The H-AR feed, with its high sulfur, metals, asphaltenes, and micro carbon residue (MCR) content, poses several challenges including carbon deposition at start of run (SOR). The observed deactivation rate is attributing to the feedstock’s poor quality and its impact associated deposition of coke and metals (V and Ni) deposition with TOS.