Heavy Metals Present in the Soils from Extremely Large Opencast Iron Mine Pit.

Abstract

The mining areas have faced severe pollution by caustic metals. In this study, heavy metals (Cu, Zn, Cr, Cd, Pb and Ni) in the soil of an extremely large iron mine pit from Ningwu-Luohe metallogenic belt, one of the seven iron ore areas in China was characterized. SiO2 was predominant soil mineral composition as 57.0 ± 1.3 %, followed by considerable Al2O3 (23.1 ± 2.5 %) and Fe2O3 (8.58 ± 1.2 %). Cu, Zn, Cr, Cd, Pb and Ni had the range of 7.62-237, 97.8-313, 1.73-43.8, 0.119-0.512, 5.13-44.7 and 7.87-23.9mg/kg, respectively, wherein, Cu, Zn, Cr and Pb were likely to have relatively low concentration in the soil from the boom of mining pit. Comparatively, both Cu and Zn arose at the level of 1-fold higher than that of local background values, indicating that the soil from mining pit had been subjected to Cu and Zn accumulation. BCR (European Communities Bureau of Reference) sequential extraction analysis showed that these metals mainly existed in residual fraction, with averaged percentages of 42.0 ± 18 %, 70.3 ± 8.1 %, 76.6 ± 18 %, 30.2 ± 14 %, 52.5 ± 11 % and 61.0 ± 9.7 % for Cu, Zn, Cr, Cd, Pb and Ni, respectively. Geo-accumulation index indicates that the soil was moderately contaminated by Cu, practically uncontaminated or uncontaminated to moderately contaminated by Zn, while practically uncontaminated by Cr, Cd, Pb and Ni. There were just significant relationships between Zn and Cd and between Cd and Pb, indicating that Cd in the soil investigated possibly had at least two sources and for most of the elements the sources were different. The effects of pit depth and major soil composition on the distribution of trace metals varied depending on the element itself and its chemical forms.