Abstract

The combination of industrial and domestic wastewater in municipal WWTPs (waste water treatment plants) may be economically profitable, but it increases the difficulty of treatment, and also has some detrimental effects on the biomass and causes a low-quality final effluent. The present study evaluates the treatment process both in the presence and absence of heavy metals using ASM3 (activated sludge model no.3) so as to improve the model by means of incorporating other novel inhibitory kinetic and settler models. The results reveal that the presence of heavy metal, a case study for copper and cadmium at a concentration of 0.7 mgL−1 in a biological treatment system has a negative effect on heterotrophic bacteria concentration by 25.00 %, and 8.76 % respectively. Meanwhile, there are no important changes in COD (chemical oxygen demand), SS (total suspended solids) and TN (total nitrogen) in the final effluent in the conventional system. However, all these parameters are acceptable and consistent with EU Commission Directives. The results indicate that ASM3 can predict and provide an opportunity of the operation for an activated sludge wastewater treatment plant that receives the effluent from an industrial plant.

Highlights

  • Industrial wastewater discharged from the industries such as textile dyeing, petroleum, metal finishing, automobile, electro-plating, and leather tanning cause heavy metals entering into the life cycle

  • During simulations the results shows the changes in the concentrations of heterotrophs with respect to time at the end of start-up period, conditioning period and operating period are given in the Figures 1 and 2 with or without heavy metals having a concentration of 0.7 mgL−1

  • The main contribution of this study is to improve ASM3 by combination with novel inhibitory kinetic models to assess the impact on the operation of an activated sludge wastewater treatment plant that receives the effluent of an industrial plant

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Summary

Introduction

Industrial wastewater discharged from the industries such as textile dyeing, petroleum, metal finishing, automobile, electro-plating, and leather tanning cause heavy metals entering into the life cycle. This becomes one the most important environmental problem in the world. There are many treatment technologies applied for the removal of heavy metals from wastewaters. Ong et al [2] give the following ranking of the toxicity of the heavy metals for biological treatment: Cd > Cu > Zn > Cr > Pb, which differs from previously mentioned rankings as these have focused on the human organism. The concerns on metals in urban wastewater treatment plants (WWTPs) are mainly related to its contents in discharges to environment, namely in the final effluent and in the sludge produced. Concerning the sludge, at least seven metals (Cd, Cr, Cu, Hg, Ni, Pb and Zn) have been regulated in different countries, four of which were classified by EUWFD as priority substances and two of which were classified as hazardous substances

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