Heavy Metal Pollution of Soil and Crops in Rural Gujarat, Next to an Industrial Area: A Correlation Study

Abstract

Heavy metal contamination is one of the significant concerns of environmental pollution. The present study was conducted to find out the correlation between soil and crop/food matrices grown at the exact location for Al, As, Ca, Cd, Cr, Cu, Fe, Hg, K, Mg, Mn, Ni, Na, P, Zn, and Pb elements near the industrial areas of Narol, Changodar, Vatva, Makarpura, Nandesari, and Ankleshwar in Gujarat, India. Soil samples were collected from 64 sampling sites in an industrial area. Twenty of these sites contained crop/food matrices used for the correlation study. The ranges of concentration of Cr (17-74.4 mg.kg-1), Cu (9.6-82.4 mg.kg-1), Ni (10.6-55.9 mg.kg-1), Pb (4.5- 20.7 mg.kg-1), Zn (21.5-112.4 mg.kg-1), and Al (7075-44557.5 mg.kg-1) for Soil and for crop Cr (0.3-0.6 mg.kg-1), Cu (0.3-8.6 mg.kg-1), Zn (1.1-43.5 mg.kg-1), Fe (12.6-69.4 mg.kg-1), and Al (5.8-102.2 mg.kg-1). According to the study, there is a strong correlation between the soil and crop/food matrices at the different locations, like 0.97 for Fe and Ni, 0.94 for Mg, 0.95 for Mn, and 0.55 for Pb and Zn, and very little correlation between K, P, and Ca, while a negative correlation between Al, Cr, Cu, and Na. The DTPA extractable method was used for the elemental analysis, and analysis was done using the ICP-OES instrument following microwave-assisted digestion. The results show that metal contamination transforms from soil to crop/food matrices, which represents a serious concern and requires action to address the metal contamination by industrialization.