Heavy-Metal Fractions in Solid and Liquid Separates of Swine Slurry Separated using Different Technologies.

Abstract

Accumulation of metals is a concern with continuous application of swine slurry to agricultural soils. Solid-liquid separation is a promising approach for reducing phosphorus and total metal loadings with swine manure application to farmlands. However, very little work has been performed on the partitioning of different metal fractions in swine slurry to separated solids and liquids. This study examined the distribution of various metal fractions in raw manures (RM), their separated liquids (SL), and separated solids (SS). The three separation techniques used were centrifuge without flocculant (CNF), centrifuge with flocculant (CFL), and rotary press with flocculant (RFL). Concentrations of Cd, Cu, Zn, Ni, and Se in manure and separates were determined by a modified Sposito's sequential chemical fractionation scheme to extract water-soluble, exchangeable, organically bound, carbonate-precipitated, and residual fractions. The greatest concentrations of metals were recovered in the residual fraction, with the organically bound and carbonate-precipitated concentrations much greater than water-soluble and exchangeable fractions. Separation index () (i.e., percentage partitioned to SS) ranged from 13 to 66%, 9 to 87%, 16 to 93%, and 23 to 96% for water-soluble, exchangeable, organically bound, and carbonate-precipitated fractions, respectively. The values in general, were significantly ( < 0.05) greater for flocculant-based separation techniques than for CNF. For organically bound and carbonate-precipitated fractions, the greatest was obtained with the RFL for most metals. Our results suggest that applying the SL from RFL separation would minimize metal loading to farmlands compared with SL from CNF and CFL techniques. However, further validation is required using more sources of manure and different flocculants.